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[PDF] BARC Exam Chemistry Syllabus
in: BARC Chemistry Syllabus[PDF] BARC Exam Chemistry Syllabus
Chemistry for BARC Exam (Tentative Syllabus)
PHYSICAL CHEMISTRY
Basic Mathematical Concepts: Functions; maxima and minima; integrals; ordinary differential equations; vectors and matrices; determinants; elementary statistics and probability theory.Atomic and Molecular Structure: Fundamental particles; Bohr’s theory of hydrogen-like atom; wave-particle duality; uncertainty principle; Schrödinger’s wave equation; quantum numbers; shapes of orbitals; Hund’s rule and Pauli’s exclusion principle; electronic configuration of simple homonuclear diatomic molecules.
Theory of Gases: Equation of state for ideal and non-ideal (van der Waals) gases; Kinetic theory of gases; Maxwell-Boltzmann distribution law; equipartition of energy.
Solid state: Crystals and crystal systems; X-rays; NaCl and KCl structures; close packing; atomic and ionic radii; radius ratio rules; lattice energy; Born-Haber cycle; isomorphism; heat capacity of solids.
Chemical Thermodynamics: Reversible and irreversible processes; first law and its application to ideal and nonideal gases; thermochemistry; second law; entropy and free energy; criteria for spontaneity.
Chemical and Phase Equilibria: Law of mass action; Kp, Kc, Kx and Kn; effect of temperature on K; ionic equilibria in solutions; pH and buffer solutions; hydrolysis; solubility product; phase equilibria–phase rule and its application to one-component and two-component systems; colligative properties.
Electrochemistry: Conductance and its applications; transport number; galvanic cells; EMF and free energy; concentration cells with and without transport; polarography; concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes. Chemical Kinetics: Reactions of various order; Arrhenius equation; collision theory; transition state theory; chain reactions – normal and branched; enzyme kinetics; photochemical processes; catalysis.
Adsorption: Gibbs adsorption equation; adsorption isotherm; types of adsorption; surface area of adsorbents; surface films on liquids.
Spectroscopy: Beer-Lambert law; fundamental concepts of rotational, vibrational, electronic and magnetic resonance spectroscopy.
ORGANIC CHEMISTRY
Basic Concepts in Organic Chemistry and Stereochemistry: Electronic effects (resonance, inductive, hyperconjugation) and steric effects and its applications (acid/base property); optical isomerism in compounds with and without any stereocenters (allenes, biphenyls); conformation of acyclic systems (substituted ethane/n-propane/n-butane) and cyclic systems (mono- and di-substituted cyclohexanes).Organic Reaction Mechanism and Synthetic Applications: Chemistry of reactive intermediates (carbocations, carbanions, free radicals, carbenes, nitrenes, benzynes etc…); Hofmann-Curtius-Lossen rearrangement, Wolff rearrangement, Simmons-Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Wittig reaction and McMurry reaction; Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienone-phenol rearrangement, Baeyer-Villeger reaction; oxidation and reduction reactions in organic chemistry; organometallic reagents in organic synthesis (Grignard, organolithium and organocopper); Diels-Alder, electrocyclic and sigmatropic reactions; functional group inter-conversions and structural problems using chemical reactions.
Qualitative Organic Analysis: Identification of functional groups by chemical tests; elementary UV, IR and 1H NMR spectroscopic techniques as tools for structural elucidation.
Natural Products Chemistry: Chemistry of alkaloids, steroids, terpenes, carbohydrates, amino acids, peptides and nucleic acids.
Aromatic and Heterocyclic Chemistry: Monocyclic, bicyclic and tricyclic aromatic hydrocarbons, and monocyclic compounds with one hetero atom: synthesis, reactivity and properties.
INORGANIC CHEMISTRY
Periodic Table: Periodic classification of elements and periodicity in properties; general methods of isolation and purification of elements. Chemical Bonding and Shapes of Compounds: Types of bonding; VSEPR theory and shapes of molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lattice energy.Main Group Elements (s and p blocks): General concepts on group relationships and gradation in properties; structure of electron deficient compounds involving main group elements.
Transition Metals (d block): Characteristics of 3d elements; oxide, hydroxide and salts of first row metals; coordination complexes: structure, isomerism, reaction mechanism and electronic spectra; VB, MO and Crystal Field theoretical approaches for structure, color and magnetic properties of metal complexes; organometallic compounds having ligands with back bonding capabilities such as metal carbonyls, carbenes, nitrosyls and metallocenes; homogenous catalysis.
Bioinorganic Chemistry: Essentials and trace elements of life; basic reactions in the biological systems and the role of metal ions, especially Fe2+, Fe3+, Cu2+ and Zn2+; structure and function of hemoglobin and myoglobin and carbonic anhydrase.
Instrumental Methods of Analysis: Basic principles; instrumentations and simple applications of conductometry, potentiometry and UV-vis spectrophotometry; analysis of water, air and soil samples.
Analytical Chemistry: Principles of qualitative and quantitative analysis; acid-base, oxidation-reduction and complexometric titrations using EDTA; precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.
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BARC Exam Chemistry (Tentative Syllabus) BARC Exam details- Find here
SSC JE 2018 Official Notification, Syllabus, Previous Papers, Study Material & Application Link
in: JE SSC SSC JESSC JE 2018 Official Notification, Syllabus, Application Link
Staff Selection Commission Junior Engineer
Junior Engineer (Civil, Electrical, Mechanical, Quantity Surveying & Contracts) Examination-2018
Name of the post- Junior Engineer
Details of Posts- Check here
Vacancies- will be determined in due course
Pay Scale- Rs 35400/- to 112400/-
Eligible Branches- Civil, Electrical & Mechanical
Eligibility criteria- Check here
Eligible- who completed Diploma/Degree till 1 Aug 2019
Application Fee- Rs 100/- Only
Scheme of Examination- Check here
Syllabus- Check here
SSC JE Post Preference for all Branches- check here
Important Dates
Submission of Online application- 01-02-2019 to 25-02-2019
Last Date for receipt of application- 25-02-2019 Till 5PM
Last Date of Online Fee Payment- 27-02-2019 Till 5PM
Last Date for Generation of Offline Challan- 27-02-2019 Till 5PM
Last Date of Payment through Challan- 28-02-2019
Exam Date
Paper-I (Computer Based)- 23-09-2019 to 27-09-2019
Paper-II (Conventional)- 29-12-2019
Previous Papers- Check here
Paper-I: Find here
SSC JE 2018 Papers- Find here
Study Materials- Find here
Must read topics- Check here
SSC JE 2018 Tentative Vacancies for All Branches
in: JE RECRUITMENT SSCSSC JE 2018 Tentative Vacancies for All Branches
Staff Selection Commission
Tentative Vacancy of Junior Engineer (Civil, Mechanical, Electrical and Quantity Surveying & Contracts) Examination, 2018
S
|
Organization
|
Post
|
SC
|
ST
|
OBC
|
UR
|
Total
|
OH
|
HH
|
1
|
CWC
|
JE(Civil)
|
18
|
18
|
40
|
72
|
148
|
3
|
3
|
2
|
CWC
|
JE (ME)
|
2
|
2
|
4
|
8
|
16
|
1
|
0
|
3
|
CPWD
|
JE (CE)
|
43
|
21
|
77
|
147
|
288
|
4
|
4
|
4
|
CPWD
|
JE (EE)
|
28
|
14
|
50
|
99
|
191
|
3
|
3
|
5
|
MES
|
JE(CE)
|
19
|
4
|
14
|
39
|
76
|
1
|
0
|
6
|
MES
|
JE(EE & ME)
|
5
|
5
|
14
|
19
|
43
|
2
|
0
|
7
|
MES
|
JE(QS&C)
|
3
|
2
|
7
|
14
|
26
|
1
|
0
|
8
|
Farakka Barrage Project
|
JE (CE)
|
4
|
1
|
6
|
4
|
15
|
0
|
0
|
9
|
Farakka Barrage Project
|
JE (EE)
|
0
|
0
|
0
|
1
|
1
|
0
|
0
|
10
|
Farakka Barrage Project
|
JE
|
0
|
0
|
0
|
1
|
1
|
0
|
0
|
11
|
Border Road Organization
|
JE (CE)
|
114
|
57
|
207
|
389
|
767
|
0
|
0
|
12
|
Central Water and Power Research Station
|
JE (CE)
|
0
|
1
|
1
|
1
|
3
|
1
|
0
|
13
|
Central Water and Power Research Station
|
JE (ME)
|
0
|
0
|
0
|
1
|
1
|
0
|
0
|
14
|
Directorate of Quality Assurance (Naval)
|
JE (ME)
|
2
|
2
|
1
|
6
|
11
|
0
|
0
|
15
|
Directorate of Quality Assurance (Naval)
|
JE (EE)
|
2
|
2
|
2
|
8
|
14
|
0
|
0
|
Total
|
240
|
129
|
423
|
809
|
1601
|
16
|
10
|
CPWD= Central Public Works Department
MES= Military Engineering Services
QS&C= Quantity Surveying & Contracts
EE= Electrical Engineering
ME= Mechanical Engineering
CE= Civil Engineering
QS&C= Quantity Surveying & Contracts
EE= Electrical Engineering
ME= Mechanical Engineering
CE= Civil Engineering
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